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Cluster synthesis by the reactions of [Cp'2M2S4] with metal complexes (Cp' = Cp and substituted cyclopentadienyl ligands, M = Fe, Ru). Masaaki Okazaki, Masahiro Yuki, Katsuaki Kuge, and Hiroshi Ogino, Coord. Chem. Rev., 198, 367-378
Synthesis and structures of bis(silylene)iron complexes containing new six-membered chelate rings. Hiromi Tobita, Takahiro Sato, Masaaki Okazaki, and Hiroshi Ogino, J. Organomet. Chem., 611, 314-322 (2000).
Synthesis of cationic diiron complexes bridged by a base-stabilized gallium atom [Fp2(μ-Ga・Do2)]+X- (Fp = (η-C5H5)Fe(CO)2, Do2 = 2,2'-bipyridine, N, N, N', N' - tetramethylethylenediamine, 1,10-phenanthroline, (4-(dimethylamino)pyridine)2, X- = [Fp2GaCl2]-, BPh4-). Keiji Ueno, Takahito Watanabe, and Hiroshi Ogino, Organometallics, 19, 5679-5682 (2000).
Coordination compounds of monoborane-Lewis base adducts: syntheses and structures of [M(CO)5(η1-BH3・L)] (M = Cr, Mo, W; L = NMe3, PMe3, PPh3). Mamoru Shimoi, Shin-ichiro Nagai, Madoka Ichikawa, Yasuro Kawano, Kinji Katoh, Mikio Uruichi, and Hiroshi Ogino, J. Am. Chem. Soc., 121, 11704-11712 (1999).
Synthesis, structure, and reactivity of germyl(germylene)tungsten complexes. Keiji Ueno, Koji Yamaguchi, and Hiroshi Ogino, Organometallics, 18, 4468-4470 (1999).
Synthesis of new paramagnetic heterodinuclear complexes with dithiolene bridging ligans, (Ph2C2S2)Fe(Cp'Ru)(μ-Ph2C2S2)2(Cp' = η5 - C5H4SiMe3(CpS1), η5 - C5Me5(Cp*)), by replacement of a metal fragment. Katsuaki Kuge, Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1999, 1075-1076.
Cluster synthesis by the reactions of [Cp'2Fe2S4] with transition-metal complexes (Cp' = C5Me5, 1,3-C5H3(SiMe3)2). Masahiro Yuki, Katsuaki Kuge, Masaaki Okazaki, Toshiaki Mitsui, Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino, Inorg. Chim. Acta, 291, 395-402 (1999).
Synthesis and structures of two isomeric pairs of tetrathiotungstate clusters, [{Cp*Ru(CO)}2(WS4){W(CO)4}] and [{Cp*Ru(CO)}2(WS4)] (Cp* = η5-C5Me5), by reaction of [Cp*2Ru2S4] with [W(CO)3(NCMe)3]. Masahiro Yuki, Masaaki Okazaki, Shinji Inomata, and Hiroshi Ogino, Organometallics, 18, 3728-3736 (1999).
Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]2(μ3-S2)W(CO)5 and Cp2Fe2(CO)2(μ-CO)(μ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex. Katsuaki Kuge, Hiromi Tobita, and Hiroshi Ogino, Chem. Commun, 1999, 1061-1062.
Synthesis, crystal structures, and fluxional behavior of donor-bridged bis(silylene)molybdenum and -chromium complexes. Keiji Ueno, Akira Masuko, and Hiroshi Ogino, Organometallics, 18, 2694-2699 (1999).
Stepwise construction of clusters containing Ru2Pt2WS4 cores by the thermal reaction of [{Cp*Ru(CO)}2(WS4)](Cp* = η5-C5Me5) with [PtMe2(cod)](cod = 1,5-cyclooctadiene). Masahiro Yuki, Masaaki Okazaki, and Hiroshi Ogino, Chem. Lett., 1999, 649-650.
Extremely Facile Arene Exchange on a Ruthenium(II) Complex Having a Novel Bis(silyl) Chelate Ligand (9,9-Dimethylxanthene-4,5-diyl)bis(dimethylsilyl) (Xantsil). Hiromi Tobita, Kenji Hasegawa, Jim Josephus Gabrillo Minglana, Lung-Shiang Luh, Masaaki Okazaki, and Hiroshi Ogino, Organometallics, 18, 2058-2060 (1999).
Synthesis and structure of the cationic external donor-stabilized silyleneiron complex [Cp(OC)2Fe=Si(p-Tol)2 HMPA]PF6 by Hydride Abstraction from a (Hydrosilyl)iron Complex. Hideki Kobayashi, Keiji Ueno,and Hiroshi Ogino, Chem. Lett., 1999, 239-240.
Formation of acyliron complexes CpFe(CO){P(OR')3}COR' by reaction of silyliron complexes CpFe(CO)2SiR3 with alkylphosphites P(OR')3. Hideki Kobayashi, Keiji Ueno, and Hiroshi Ogino, Chem. Lett., 1999, 119-120.
Preparation of silanediyl-bridged Fe-Fe and Fe-W dinuclear complexes. X-ray structures of [Cp*Fe(CO)(μ-CO){μ-Si(H)CHPh2}(CO)nMCp] (Cp* = C5Me5, Cp = C5H5, M = Fe, n = 1; M = W, n = 2). Lung-Shiang Luh, Yuh-Sheng Wen, Hiromi Tobita, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 71, 2865-2871 (1998).
Formation of isomeric tetrathiotungstate clusters [{Cp*Ru(CO)}2(WS4){W(CO)4}] by the reaction of [Cp*2Ru2S4] with [W(CO)3(MeCN)3]. Masahiro Yuki, Masaaki Okazaki, Shinji Inomata, and Hiroshi Ogino, Angew. Chem., Int. Ed., 37, 2126-2128 (1998).
Fluxional behavior of alkoxy-bridged bis(silylene)ruthenium complexes Cp*(Me3P)Ru{SiMe2・・・O(R)・・・SiMe2} (R = Me, tBu) caused by rotation of the silylene ligands. Hiroaki Wada, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1998, 993-994 (1998).
Abiological iron-sulfur clusters. Hiroshi Ogino, Shinji Inomata, and Hiromi Tobita, Chem. Rev., 98, 2093-2121 (1998).
Reductive coupling of carbonyl ligands on a cubane-type tetrairon cluster [Cp4Fe4(CO)4] or [(MeC5H4)4Fe4(CO)4] to give an acetylene-coordinated cluster [Cp4Fe4(HC≡CH)2] or [(MeC5H4)4Fe4(HC≡CH)2]. Masaaki Okazaki, Takeo Ohtani, Shinji Inomata, Naohiko Tagaki, and Hiroshi Ogino, J. Am. Chem. Soc., 120, 9135-9138 (1998).
Novel reaction of silyl carbonyl complexes with hydride-transfer reagents: Reduction of a carbonyl ligand and coupling with a silyl group. Rie Shiozawa, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 17, 3497-3504 (1998).
Thermal and photochemical reactions of a cationic rhenocene-acetonitrile adduct: The first C-H bond activation by rhenocene cation. Hiromi Tobita, Kiyonari Hashidzume, Kouji Endo, and Hiroshi Ogino, Organometallics, 17, 3405-3407 (1998).
Synthesis and properties of intramolecularly base-stabilized (disilanyl-silylene)ruthenium and -iron complexes. Hiromi Tobita, Hitoe Kurita, and Hiroshi Ogino, Organometallics, 17, 2850-2856 (1998).
Synthesis, structure, and reactivity of a bis(silylene)carbonyl ruthenium complex and a novel addition reaction of photochemically generated dimethylsilylene to bis(silylene) complexes Cp(OC)M{SiMe2…O(Me)…SiMe2} (M = Ru, Fe). Hiromi Tobita, Hitoe Kurita, and Hiroshi Ogino, Organometallics, 17, 2844-2849 (1998). .
Bridged silylene and germylene complexes. Hiroshi Ogino and Hiromi Tobita, Adv. Organomet. Chem., 42, 223-290 (1998).
Thermal reactions of alkyl(hydrido)(hydrosilyl)iridium(III) complexes: Generation of a hydrido(silylene)iridium(I) species via the reductive elimination of alkane and 1,2-H-shift from the silicon atom to the Ir(I) metal center. Masaaki Okazaki, Hiromi Tobita, Yasuro Kawano, Shinji Inomata, and Hiroshi Ogino, J. Organomet. Chem., 553, 1-13 (1998).
Synthesis, structure, and fluxional behavior of base-stabilized silyl(silylene)tungsten complexes. Keiji Ueno, Mihoko Sakai, and Hiroshi Ogino, Organometallics, 17, 2138-2140 (1998).
Photon-, reductant-, and oxidant-induced substitution of a CO ligand on closo-[Cp*2Fe3S2(CO)3] (Cp* = η5 - C5Me5). Masahiro Yuki, Toshiaki Mitsui, Shinji Inomata, Masaaki Okazaki, and Hiroshi Ogino, Chem. Lett., 1998, 561-562 (1998).
Kinetic study of the skeletal inversion in a tetrairon-sulfur cluster {η5 - C5H4(SiMe3)}4Fe4S6. Hiromi Tobita, Mikiya Yamada, Shinji Inomata, and Hiroshi Ogino, Chem. Lett., 1998, 507-508 (1998).
Synthesis and structure of a dinuclear cobalt complex bridged by nonsubstituted borylene-trimethylphosphine. Mamoru Shimoi, Sachiko Ikubo, Yasuro Kawano, Kinji Katoh, and Hiroshi Ogino, J. Am. Chem. Soc., 120, 4222-4223 (1998).
Synthesis and reactivity of triiron complexes containing selenide and diselenide bridging ligands: X-ray structure of [Cp*3Fe3(μ2-Se)(μ3-Se2)2](PF6) (Cp* = η5-C5Me5). Shinji Inomata, Takehiko Hiruma, and Hiroshi Ogino, Chem. Lett., 1998, 309-310 (1998).
Synthesis of cationic germyleneiron complexes and X-ray structure of [Cp*(CO)2Fe = GeMe2・DMAP]BPh4・CH3CN (Cp* = C5Me5, DMAP = 4-(Dimethylamino)pyridine). Hiromi Tobita, Kaoru Ishiyama, Yasuro Kawano, Shinji Inomata, and Hiroshi Ogino, Organometallics, 17, 789-794 (1998)..
Reactions of [chloro(1,2-phenylenedioxy)silyl]iron complex Cp(CO)2FeSiCl(o-O2C6H4) with nucleophiles. Koji Yamaguchi, Keiji Ueno, and Hiroshi Ogino, Chem. Lett., 1998, 247-248 (1998).
Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex ミFormation of a {(2-phosphinoethyl)}(ethene)iridium(I) complexミ. Masaaki Okazaki, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1998, 69-70 (1998).
Synthesis of the first iron complexes containing 1,2-phenylenedioxysilyl group. Koji Yamaguchi, Keiji Ueno, and Hiroshi Ogino, Chem. Lett., 1998, 37-38 (1998).
Synthesis, structure, and fluxional behavior of donor-stabilized bis(silylene)tungsten complexes. Keiji Ueno, Akira Masuko, and Hiroshi Ogino, Organometallics, 16, 5023-5026 (1997).
Addtions and Corrections
Quantitative transfer of a methyl group from a methyl(hydrido)iridium complex to SiRH3 (R = n-butyl, pentyl or hexyl) to give SiR(Me)H2 and a dihydridoiridium complex. Masaaki Okazaki, Hiromi Tobita, and Hiroshi Ogino, J. Chem. Soc., Dalton Trans., 1997, 3531-3533 (1997).
Synthesis and structure of [Cp*3(Ph2C2S2)Fe4S5](BF4)・Me2CO: Implication of the flexible Fe4S5 framework. Shinji Inomata, Keiichi Hitomi, and Hiroshi Ogino, Chem. Lett., 1997, 1169-1170 (1997).
Intramolecular aromatic C-H bond activation by a silylene ligand in a methoxy-bridged bis(silylene)-ruthenium complex. Hiroaki Wada, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 16, 3870-3872 (1997).
Synthesis and properties of s-alkyl-substituted silanediyl-bridged and silanetriyl-bridged diiron complexes, Cp2(CO)2Fe2(μ-CO)[μ-Si(X)CHR2] and Cp2(CO)2Fe2(μ-CO)[μ-Si(DMAP)CHR2]+I- (X = H, I; R = Et, Ph; DMAP = 4-(Dimethylamino)pyridine). Lung-Shiang Luh, Yuh-Sheng Wen, Hiromi Tobita, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 70, 2193-2200 (1997).
Reactivity of a donor-stabilized bis(silylene)ruthenium complex toward nucleophiles ROH (R = Me, H). Hiroaki Wada, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 16, 2200-2203 (1997).
Reaction of silyl(carbonyl)iron complexes with LiAlH4 giving methylsilanes: Reduction of a carbonyl ligand and coupling with a silyl group. Hiromi Tobita, Rie Shiozawa, and Hiroshi Ogino, Chem. Lett., 1997, 805-806 (1997).
Synthesis and cyclization reaction of cis,cis-1,3,5-triformyl-1,3,5-trimethylcyclohexane. Hiroshi Izumi, Osamu Setokuchi, Yukio Shimizu, Hiromi Tobita, and Hiroshi Ogino, J. Org. Chem., 62, 1173-1175 (1997).
Iridium-catalyzed redistribution of hydrodisilanes via a silyl(silylene)iridium(III) complex: Synthesis of a donor-stabilized silyl(silylene)iridium(III) complex. Masaaki Okazaki, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1997, 437-438 (1997).
Volumetric study on a Co(III) rotaxane complex in aqueous solutions at 25℃. K. Takaizumi, T. Wakabayashi, and H. Ogino, J. Solution Chem., 25, 947-953 (1996).
Photoreaction of silyliron(II) complex Cp*Fe(CO)2SiMe3 (Cp* = η5-C5Me5) in the presence of p-tolylgermane. Amr El-Maradny, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 15, 4954-4958 (1996).
Synthesis and structure of the {(2-phosphinoethyl)silyl}tris(tertiary phosphine)iridium(I) complex Ir{η2-Me2Si(CH2)2PPh2}(PMe3)3. Masaaki Okazaki, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 15, 2790-2793 (1996).
Generation of hydrido(silylene)iridium(I) complex via [1,2] H shift from the silicon atom to the iridium(I) metal center. Masaaki Okazaki, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1996, 477-478 (1996).
Synthesis of a donor-stabilized silyl(silylene)iron complex. Direct observation of 1,3-methyl migration from silyl to silylene ligands. Keiji Ueno, Kaori Nakano, and Hiroshi Ogino, Chem. Lett., 1996, 459-460 (1996).
Isolation and structural characterization of complexes formed in the reactions of [{C5H4(SiMe3)}2Fe2(CO)4] and [{1,3-C5H3(SiMe3)2}2Fe2(CO)4] with elemental sulfur. Mikiya Yamada, Hiromi Tobita, Shinji Inomata, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 69, 861-867 (1996).
Photoreactions of silyliron(II) complexes Cp'Fe(CO)2SiMe3 (Cp' = η5-C5H5, η5-C5Me5)with Di-p-tolylgermane (p-Tol)2GeH2. Amr El-Maradny, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1996, 83-84 (1996).
Synthesis of the cationic silyleneiron complex [(η-C5H5)Fe(CO)2=SiMe{2-(Me2NCH2)C6H4}]PF6 by hydride abstraction from a (hydrosilyl)iron complex with Ph3CPF6. Hideki Kobayashi, Keiji Ueno, and Hiroshi Ogino, Organometallics, 14, 5490-5492 (1995).
Light and heat-induced geometric isomerization of chloro(hydrido)iridium(III) complex containing a (2-phosphinoethyl)silyl chelate ligand. Masaaki Okazaki, Yasuro Kawano, Hiromi Tobita, Shinji Inomata, and Hiroshi Ogino, Chem. Lett., 1995, 1005-1006 (1995).
Redistribution reactions of hydrosilanes mediated by the unsymmetrical and homometallic phosphido-bridged complex (η5-C5Me5)Fe2(CO)2(μ-CO)(μ-PPh2). Hisako Hashimoto, Hiromi Tobita, and Hiroshi Ogino, J. Organomet. Chem., 499, 205-211 (1995).
Silylene-bridged dinuclear complexes having a triplet ground state: Photochemical synthesis and structural characterization of Cp2Fe2(μ-CO)2(μ-SiR2) (Cp = η5-C5H5; R = 2,4,6-C6H2iPr3, 2,6-C6H3Et2, and mesityl). Hiromi Tobita, Hiroshi Izumi, Setsuko Ohnuki, Miles C. Ellerby, Mami Kikuchi, Shinji Inomata, and Hiroshi Ogino, J. Am. Chem. Soc., 117, 7013-7014 (1995).
Kinetic study of interconversion between two geometrical isomers of the methoxy-bridged bis(silylene)iron complex, (η-C5Me5)(OC)Fe{(SiMe2)…OMe…(SiMeOMe)}. Keiji Ueno and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 68, 1955-1958 (1995).
低原子価ケイ素およびゲルマニウムを配位した遷移金属錯体の合成と性質 (Synthesis and properties of transition-metal complexes coordinated with low-valent silicon and germanium). 飛田博実, 荻野博, 有機合成化学協会誌, 53, 530-540 (1995).
Synthesis and structure of a diiron complex with a highly bent dithiolene bridge, Cp*2Fe2(CO){S2C2(CO2Me)2} (Cp* = η5-C5Me5). Shinji Inomata, Hidehiro Takano, Kunimasa Hiyama, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 14, 2112-2114 (1995).
Correction: Organometallics, 15, 2418 (1996).
Electrochemistry of octamethyl[3]ruthenocenophane: Synthesis and structure of the first dicationic derivative of ruthenocene, [{η5:η5-C5Me4(CH2)3C5Me4}Ru(NCMe)](PF6)2. Kiyonari Hashidzume, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 14, 1187-1194 (1995).
Syntheses and structures of mixed-ligand tetrairon-sulfur clusters: Cp*2(Ph(R)C2S2)2Fe4S4 (Cp* = Cp, R = Ph, Et; Cp* = C5Me5, R = Ph, Me, Et) and (C5Me5)3(Ph2C2S2)Fe4S5. Shinji Inomata, Kunimasa Hiyama, Hiromi Tobita, and Hiroshi Ogino, Inorg. Chem., 33, 5337-5342 (1994).
Syntheses of closo-Cp'2(CO)3Fe2MS2 clusters (Cp' = η5-C5Me5; M = Fe, Ru) and molecular structure of Cp'2(CO)3Fe3S2. Toshiaki Mitsui, Shinji Inomata, and Hiroshi Ogino, Inorg. Chem., 33, 4934-4936 (1994).
Voltammetric behavior of doubly-bridged dioxobis(dithiocarbamato)dimolybdenum(V) complexes in dichloromethane. Kei Unoura, Yoshihiro Fukase, Yojiro Sato, Nobuyuki Chida, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 67, 3122-3124 (1994).
Syntheses and structures of mixed-ligand tetrairon-sulfur clusters, [Cp'2(Ph2C2S2)2Fe4S4](PF6) and [Cp'3(Ph2C2S2)Fe4S5](PF6)n (n = 1 and 2) (Cp' = η5-C5Me5). Structural change of the clusters accompanying electron transfer reactions. Shinji Inomata, Keiichi Hitomi, Hiromi Tobita, and Hiroshi Ogino, Inorg. Chim. Acta, 225, 229-238 (1994).
Functionalization of the μ-silylene ligand in Cp2Fe2(CO)3(μ-SiHtBu): Syntheses of μ- halosilylene complexes Cp2Fe2(CO)3(μ-SiXtBu) (X = Cl, Br, I) and donor-stabilized cationic μ-silylyne complexes [Cp2Fe2(CO)3(μ-SitBu・base)]I (base = N-methylimidazole, 4-(dimethylamino)pyridine). Yasuro Kawano, Hiromi Tobita, Mamoru Shimoi, and Hiroshi Ogino, J. Am. Chem. Soc., 116, 8575-8581 (1994).
Synthesis and reactivity of the osmate(0) complexes M[Os(CO)2(η-C5R5)] (M = Li, Na; R = H, Me): Versatile synthons for synthesis of organoosmium complexes. Yasuro Kawano, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 13, 3849-3853(1994).
Synthesis and crystal structure of an amino-bridged bis(silylene)iron complex. Keiji Ueno, Shoko Ito, Ken-ich Endo, Hiromi Tobita, Shinji Inomata, and Hiroshi Ogino, Organometallics, 13, 3309-3314 (1994).
Nonphotochemical synthesis and structure of the first donor-stabilized [bis(silylene)]ruthenium complex. Hiromi Tobita, Hiroaki Wada, Keiji Ueno, and Hiroshi Ogino, Organometallics, 13, 2545-2547 (1994).
Reactions of sterically congested secondary silanes with iron carbonyls. Formation of μ-silylene complexes Fe2(CO)8(μ-SiR2) (R = mesityl and O(2,6-iPr2C6H3)). Hiromi Tobita, Isao Shinagawa, Setsuko Ohnuki, Machiko Abe, Hiroshi Izumi, and Hiroshi Ogino, J. Organomet. Chem., 473, 187-193 (1994).
Synthesis and structure of the first base-stabilized germylyne-bridged dinuclear complex [Cp2Fe2(CO)3(μ-GetBu・DMAP)]OTf (DMAP = 4-(dimethylamino)pyridine; OTf = CF3SO3). Jun Fujita, Yasuro Kawano, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1994, 1353-1356 (1994).
C-C-bond formation between (η1:η5-CH2C5Me4)Fe2(CO)6 and CS2 to give the triiron complex {(η5-C5Me4)CH2CS2}Fe3(CO)8. Hisako Hashimoto, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 13, 1055-1057 (1994).
Synthesis and properties of germylene-bridged diiron complexes using t-butylgermane as a precursor of ligands. Yasuro Kawano, Keiko Sugawara, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1994, 293-296 (1994).
Photolysis of CpFe(CO)2SiMe2SiMe2H in the presence of methanol. Indirect evidence for the transient formation of a disileneiron complex. Keiji Ueno, Seiji Seki, and Hiroshi Ogino, Chem. Lett., 1993, 2159-2162 (1993).
Threading molecular strings onto molecular rings. Synthesis of rotaxanes by use of cyclodextrins. Hiroshi Ogino, New. J. Chem., 17, 683-688 (1993).
Reactivity of alkoxy-bridged bis(silylene)iron complexes Keiji Ueno, Hiromi Tobita, Seiji Seki and Hiroshi Ogino, Chem. Lett., 1993, 1723-1726 (1993).
Synthesis of the 1,2,3,4-tetramethylfulvene-bridged diiron complex (η1:η5-CH2C5Me4)Fe2(CO)6 and its reactions with phosphines. Hisako Hashimoto, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 12, 2182-2187 (1993).
Syntheses and structures of vanadium(III) complexes containing 1,3-diaminopropane-N,N,N',N'-tetraacetate ([V(trdta)]-) and 1,3-diamino-2-propanol-N,N,N',N'-tetraacetate ([V2(dpot)2]2-). Julita C. Robles, Yoko Matsuzaka, Shinji Inomata, Mamoru Shimoi, Wasuke Mori, and Hiroshi Ogino, Inorg. Chem., 32, 13-17 (1993).
Photochemical synthesis and stereodynamic behavior of alkoxy-bridged (silylene)(germylene)iron complexes. Julian R. Koe, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 11, 2479-2483 (1992).
Silicon-silicon interaction in bis(silylene)iron, disilanyliron, and bis(silyl)iron complexes. Keiji Ueno, Hiromi Tobita, and Hiroshi Ogino, J. Organomet. Chem., 430, 93-104 (1992).
Kinetic study of isomerization reactions of (trimethylsilyl)methylsilylene-bridged diiron complexes. Keiji Ueno, Nagato Hamashima, and Hiroshi Ogino, Organometallics, 11, 1435-1437 (1992).
Photoreactions of silyliron(II) complexes Cp*Fe(CO)2SiMe3 (Cp* = η5-C5H5, η5-C5Me5) in the presence of trihydrosilanes. Yasuro Kawano, Hiromi Tobita, and Hiroshi Ogino, J. Organomet. Chem., 428, 125-143 (1992).
Syntheses and structures of [M(CO)5{B2H4・2P(CH3)3}] and [M(CO)4{B2H4・2PMe3}] (M = Cr, Mo, W). Kinji Katoh, Mamoru Shimoi, and Hiroshi Ogino, Inorg. Chem., 31, 670-675 (1992).
Synthesis and structure of mixed-ligand iron-sulfur cubane-like clusters [(η-C5Me5)3(Ph2C2S2)Fe4S5]n ( n = 0 and 1+). Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino, Inorg. Chem., 31, 722-723 (1992).
Reversible thermal and photochemical interconversion between cis and trans isomers of the silylene-bridged diiron complex Cp'2Fe2(CO)3(μ-SiHTol)(Cp' = η-C5Me5, Tol = p-CH3C6H4). Yasuro Kawano, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 11, 499-500 (1992).
Synthesis and crystal structure of the novel dinuclear vanadium(III) complex K2[V2(dpot)2]・7H2O containing 1,3-diamino-2-propanol-N,N,N',N'-tetraacetate (dpot). Julita C. Robles, Mamoru Shimoi, and Hiroshi Ogino, Chem. Lett., 1992, 309-310 (1992).
UV photolysis of digermanyliron complexes and dynamic NMR spectroscopy of alkoxy-bridged bis(germylene)iron products. Julian R. Koe, Hiromi Tobita, Tatsunori Suzuki, and Hiroshi Ogino, Organometallics, 11, 150-154 (1992).
Kinetic studies of oxygen atom transfer reactions between various cis-dioxobis(dithiocarbamato)molybdenum(VI) complexes and triphenylphosphine. Kei Unoura, Yoshikiyo Kato, Katsuaki Abe, Akio Iwase, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 64, 3372-3375 (1991).
[Cp2Fe2(CO)3(μ-SitBu・NMI)]I: The first silanetriyldiiron complex. Yasuro Kawano, Hiromi Tobita, and Hiroshi Ogino, Angew. Chem., Int. Ed. Engl., 30, 843-844, (1991).
Syntheses and crystal structures of seven-coordinate (ethylenediamine-N,N,N',N'-tetraacetato)aquavanadate(III) complexes. Mamoru Shimoi, Yoko Saito, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 64, 2629-2634 (1991).
Synthesis and crystal structure of seven-coordinate (trans-1,2-cyclohexanediamine-N,N,N',N'-tetraacetato)aquavanadate(III). Mamoru Shimoi, Shigeru Miyamoto, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 64, 2549-2550 (1991).
Electrochemical behavior of [Cp'2Fe2S4] and [Cp'2Fe2S4](PF6)2 (Cp' = η5-C5Me5): Structural change of the Fe2S4 core accompanied by a change of redox state. Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino, Inorg. Chem., 30, 3039-3043 (1991).
Photochemical conversion of a disilanylene-bridged iron dimer to silylene-bridged iron dimers. Keiji Ueno, Nagato Hamashima, Mamoru Shimoi, and Hiroshi Ogino, Organometallics, 10, 959-962 (1991).
Synthesis and structure of the first donor-stabilized bis(silylene)manganese complex. Tamiko Takeuchi, Hiromi Tobita, and Hiroshi Ogino, Organometallics, 10, 835-836 (1991).
Crystal structures of polymorphic [Fe4(η5-C5H5)4S4](PF6). Mamoru Shimoi, Asako Satoh, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 64, 11-15 (1991).
Voltammetric studies of cis-dioxobis(dithiocarbamato)molybdenum(VI) complexes.Kei Unoura, Akio Iwase, and Hiroshi Ogino, J. Electroanal. Chem., 295, 385-392 (1990).
Syntheses and crystal structures of [Cr(CO)5(B2H4・2PMe3)] and [Cr(CO)4(B2H4・2PMe3)]: the first example of a single hydrogen bridge bond between a metal and a polyborane. Mamoru Shimoi, Kinji Katoh, and Hiroshi Ogino, J. Chem. Soc., Chem. Commun., 1990, 811-812 (1990). [主]
Synthesis, structure, and electrochemical properties of mixed-ligand iron-sulfur cubane clusters with two Cp* and two dithiolene ligands (Cp* = η-C5H5, η-C5Me5). Shinji Inomata, Hiromi Tobita, and Hiroshi Ogino, J. Am. Chem. Soc., 112, 6145-6146 (1990).
First synthesis of [Fe4(η5-C5H5)4S4](PF6)3 and improved syntheses of [Fe4(η5-C5H5)4S4](PF6)n (n = 1,2). Hiroshi Ogino, Asako Satoh, and Mamoru Shimoi, Bull. Chem. Soc. Jpn., 63, 2314-2317 (1990).
Photolysis of alkoxy-substituted disilanyliron complexes: Preparation of donor-stabilized bis(silylene)iron complexes and the crystal structure of
U----------------------------------------------U
(Me2Si)--[(η5-C5Me5)Fe(CO)]--[SiMe(OMe)]--OMe. Hiromi Tobita, Keiji Ueno,Mamoru Shimoi, and Hiroshi Ogino. J. Am. Chem. Soc., 112, 3415-3420 (1990).
Kinetics of the ligand substitution reactions of a labilized ruthenium(III) complex, [Ru{N'-(2-hydroxyethyl)ethylenediamine-N,N,N'-triacetate}(H2O)] Hiroshi Ogino, Tetsuo Katsuyama, and Setsuo Ito, Bull. Chem. Soc. Jpn., 63, 1370-1373 (1990).
Syntheses and properties of [Cu{B2H4・2P(CH3)3}2]X (X = Cl, I) and X-ray crystal structure of the iodide. Mamoru Shimoi, Kinji Katoh, Hiromi Tobita, and Hiroshi Ogino, Inorg. Chem., 29, 814-817 (1990).
Evidence for equilibration of 1,3-alkyl migration in silyl(silylene)iron intermediates. Keiji Ueno, Hiromi Tobita, and Hiroshi Ogino, Chem. Lett., 1990, 369-372.
Preparation, stereoisomerism, and dynamic properties of [(η5-C5H5)2Fe2(CO)2-(μ-CO)(μ-SiXBut)] (X = Cl, Br, I, and Me). Hiromi Tobita, Yasuro Kawano, and Hiroshi Ogino, Chem. Lett., 1989, 2155-2158.
Electrochemical synthesis and structure of the first example of a ferrocene dication: propane-1,3-diyl-1,1'-bis(tetramethylcyclopentadienyl)iron(2+). Hiroshi Ogino, Hiromi Tobita, Hiroki Habazaki, and Mamoru Shimoi, J. Chem. Soc., Chem.Commun., 1989, 828-829.
Redox potentials and related thermodynamic parameters of (diamino polycarboxylato) metal(III/II) redox couples. Hiroshi Ogino, Takako Nagata, and Kazuko Ogino, Inorg. Chem., 28, 3656-3659 (1989).
Structural identification of the reactive vanadium(III) intermediate formed in the electron-transfer reactions of [N'-(2-hydroxyethyl)ethylenediamine-N,N,N'-triacetato]aqua-vanadium(III) complex ([V(hedtra)(H2O)]) with halogenopentaamminecobalt(III) complexes: X-ray crystal structures of [V(hedtra)(H2O)]・2H2O and K[VO(hedtra)]・H2O. Hiroshi Ogino, Mamoru Shimoi, and Yoko Saito, Inorg. Chem., 28, 3596-3600 (1989).
Syntheses of M[V(edta)(H2O)]・nH2O (M = Na, K, NH4) and X-ray crystal structure of Na[V(edta)(H2O)]・3H2O. Mamoru Shimoi, Yoko Saito, and Hiroshi Ogino, Chem. Lett., 1989, 1675-1678 (1989).
Electrochemical studies of μ-oxo-bis[bis(dibenzyldithiocarbamato)oxomolybdenum(V)] in dichloromethane. Kei Unoura, Masahiko Ichisima, Hitoshi Kijima, Akio Iwase, and Hiroshi Ogino, J. Electroanal. Chem., 265, 311-315 (1989).
Kinetics of the reduction of cobalt(III) amine complexes by 1-hydroxy-1-methylethyl radicals. Keiji Kusaba, Hiroshi Ogino, Andreja Bakac, and James H. Espenson, Inorg. Chem., 28, 970-972 (1989).
X-ray crystal structures of trans-(chloromethyl)bis(2,4-pentanedionato)(aqua and methanol)chromium(III) complexes. Evidence for a trans influence exerted in the carbon-bonded chromium(III) complexes. Yoichi Abe and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 62, 56-60 (1989).
Synthesis and crystal structure of [(η5-C5Me5)2Fe2S4](PF6)2. Shinji Inomata, Hiromi Tobita, Mamoru Shimoi, and Hiroshi Ogino, J. Coord. Chem., 18, 231-232 (1988).
X-ray crystal structures of cis- and trans-dinitrobis(1,4-butanediamine)cobalt(III) nitrates. Conformation of seven-membered chelate rings. Mamoru Shimoi, Yuki Fujinawa, Hiroshi Ogino, Kan Kanamori, and Kiyoyasu Kawai, Bull. Chem. Soc. Jpn., 61, 3491-3496 (1988).
Mechanistic study on the photochemical conversion of disilanyliron(II) complexes to monosilyliron(II) complexes. Hiromi Tobita, Keiji Ueno, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 61, 2797-2804 (1988).
Structural change accompanying electrochemical oxidation of [(η5-C5Me5)2Fe2S4] to [(η5-C5Me5)2Fe2S4](PF6)2. Hiroshi Ogino, Hiromi Tobita, Shinji Inomata, and Mamoru Shimoi, J. Chem. Soc., Chem. Commun., 1988, 586-587.
Synthesis, characterization, and X-ray crystal structure of a donor-stabilized bis(silylene)iron complex. Keiji Ueno, Hiromi Tobita, Mamoru Shimoi, and Hiroshi Ogino, J. Am. Chem. Soc., 110, No. 12, 4092-4093 (1988).
Synthesis and crystal structure of a dinuclear iron tetracarbonyl complex containing a ligand, η5,η5-C5Me4CH2CH2CH2C5Me4. Hiromi Tobita, Hiroki Habazaki, Mamoru Shimoi, and Hiroshi Ogino, Chem. Lett., 1988, 1041-1044.
Syntheses, characterizations, and interconversion reactions of cis- and transbis-(2,4-pentanedionato)diaquachromium(III) complexes. Application to the cleavage reactions of the chromium-carbon bonds in trans-(dichloromethyl and chloromethyl)bis(2,4-pentanedionato)aquachromium(III) complexes in aqueous solutions. Hiroshi Ogino, Yoichi Abe, and Masato Shoji, Inorg. Chem.,27, 986-989 (1988).
Kinetics and mechanism of reduction of pentaamminecobalt(III) complexes, [CoX(NH3)5]2+ (X = F, Cl, Br, N3), by [N'-(2-hydroxyethyl)ethylenediamine-N,N,N'-triacetato]aquavanadium(III). Hiroshi Ogino, Makoto Shimura, Noriko Yamamoto, and Nobuyuki Okubo, Inorg. Chem., 27, 172-175 (1988).
Photoinduced direct synthesis of the silylene-bridged dinuclear iron complexes [(η5-C5H5)2Fe2(CO)2(μ-CO)(μ-SiHR)] from [(η5-C5H5)Fe(CO)2SiMe3] and RSiH3 (R = t-Bu, (CMe2)25H). Hiromi Tobita, Yasuro Kawano, Mamoru Shimoi, and Hiroshi Ogino, Chem. Lett., 1987, 2247-2250.
Synthesis and structure of the iron-selenium cubane cluster [(η5-C5H5)4Fe4Se4]3+: The fourth member of the [(η5-C5H5)4Fe4Se4]n series (n = 0 to 4+). Hiroshi Ogino, Hiromi Tobita, Kasumi Yanagisawa, Mamoru Shimoi, and Chizuko Kabuto, J. Am. Chem. Soc., 109, 5847 (1987).
Syntheses, X-ray crystal structures, and ligand substitution kinetics of the carbon-bonded chromium(III) complexes trans-[CrR(acac)2(L)] (R = CH2Cl, CHCl2; L = H2O, CH3OH, pyridine). Hiroshi Ogino, Masato Shoji, Yoichi Abe, Makoto Shimura, and Mamoru Shimoi, Inorg. Chem., 26, 2542-2546 (1987).
Solvatochromism of [diamine-N,N'-polycarboxylato]chromium(III) and -cobalt(III) complexes. Naoko Miura, Makoto Shimura, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 60, 1349-1353 (1987).
Syntheses of many-membered chelate ring compounds. Hiroshi Ogino, J. Coord. Chem., 15, 187-218 (1987).
Fast cis-trans isomerization of square-planar bis(diethyl sulfide)platinum(II) complexes. Reaction of cis-dichlorobis(diethyl sulfide)platinum(II) with mesityllithium. Hiromi Tobita, Hiroki Habazaki, and Hiroshi Ogino, Bull. Chem. Soc. Jpn., 60, 797-799 (1987).
Photochemical conversion of disilanyliron(III) complexes to monosilyliron(III) complexes. Hiromi Tobita, Keiji Ueno, and Hiroshi Ogino, Chem. Lett., 1986, 1777-1780.
Kinetic studies on edta complexes of transition metals. Hiroshi Ogino and Makoto Shimura, Adv. Inorg. Bioinorg. Mech., 4, 107-135 (1986).
Synthesis of trans-(dichloromethyl)bis(2,4-pentanedionato)(aqua, pyridine, or methanol)-chromium(III) and crystal structure of trans-(dichloromethyl)bis(2,4-pentanedionato)pyridinechromium(III). Masato Shoji, Makoto Shimura, Hiroshi Ogino, and Tasuku Ito, Chem. Lett., 1986, 995-998.
Kinetics of the ligand substitution reactions of a labilized chromium(III) complex, [(NH3)5- Co{(edta)Cr(H2O)}]2+. Hiroshi Ogino, Akihiko Masuko, Setsuo Ito, Naoko Miura, and Makoto Shimura, Inorg. Chem., 25, 708-710 (1986).
Structural studies of thiocyanato and isothiocyanato cobalt(III) complexes ligating diamine-N,N'-polycarboxylates. Yoshikiyo Kato, Hiroaki Isago, Hiroshi Ogino, Koshiro Toriumi, and Tasuku Ito, Bull. Chem. Soc. Jpn., 58, 3506-3512 (1985).
Preparation and spectral properties of trans- and cis-dinitrobis(tetramethylenediamine)-cobalt(III). Kiyonori Nagata, Kan Kanamori, Kiyoyasu Kawai, and Hiroshi Ogino, Chem. Lett., 1985, 1507-1510.
The first dinuclear copper(II) complex bridged by a single thiolate-sulphur atom: Synthesis,properties, and structure. Nobuo Aoi, Yumiko Takano, Hiroshi Ogino, Gen-etsu Matsubayasi, and Toshio Tanaka, J. Chem. Soc., Chem. Commun., 1985, 703-704.
クロム-炭素結合を含む錯体 [Cr(CH2OH)(hedtra)]- によるコバルト(III)錯体の還元.志村眞, 荻野博, 田中信行, 日化, 1985, 370-372.
Kinetics of the cleavage of the chromium-carbon bond in N-2-hydroxyethylethylenediamine-N,N',N'-triacetato(hydroxymethyl)chromium(III) and nitrilotriacetato(hydroxymethyl)-aquachromium(III). Makoto Shimura, Hiroshi Ogino, and Nobuyuki Tanaka, Chem. Lett., 1985, 149-150.
Syntheses and properties of rotaxane complexes. 2. Rotaxanes consisting of α- or β-cyclodextrin threaded by (μ-α,ω-diaminoalkane)bis[chlorobis(ethylenediamine)-cobalt(III)] complexes. Hiroshi Ogino and Kazuya Ohata, Inorg. Chem., 23, 3312-3316 (1984).
Syntheses, characterizations, and kinetic aspects of thiocyanato and isothiocyanato linkageisomers of cobalt(III) complexes ligating aminopolycarboxylates. Hiroshi Ogino and Hiroaki Isago, Chem. Lett., 1984, 561-564.
Kinetics and mechanism of the acetate assisted cleavage of the chromium-carbon bond of hydroxymethylpentaaquachromium(III). Hiroshi Ogino, Makoto Shimura, and Nobuyuki Tanaka, J. Chem. Soc., Chem. Commun., 1983, 1063-1064.
Redox potentials and related parameters of cobalt(III/II) complexes containing aminopolycarboxylates. Hiroshi Ogino and Kazuko Ogino, Inorg. Chem., 22, 2208-2211 (1983).